Chelsea's clash against Manchester United and the north London derby at the Emirates Stadium are among the matches Sky have added to their Premier League coverage in the months of October and November.
The broadcaster confirmed on Friday that they will show 45 top-flight games up until November - which includes the eagerly-anticipated match between Antonio Conte's champions and Jose Mourinho's side at Stamford Bridge on November 5.
That day will also see Sky show Manchester City vs Arsenal while the broadcaster has confirmed that Arsenal's derby clash against Tottenham at the Emirates Stadium will be shown live on November 19.
Spurs, who will spend the season playing in their temporary home at Wembley, will have their match against Liverpool broadcast on October 22 while their away trip to take on United at Old Trafford will be aired on October 28.
Liverpool's game against fierce rivals United at Anfield will be broadcast on October 14.
Speaking about the new Premier League season, which Arsenal will kick off against Leicester on Friday night, Sky Sports' head of Football, Gary Hughes, said: "With 20 more exclusively live matches, the Sky Sports Premier League channel will continue to follow every team in depth like never before.
"From The Debate and Premier League Prediction shows to Soccer AM, Gillette Soccer Saturday and more - fans will get the whole story."
BT Sport, meanwhile, will broadcast 42 matches with the bulk being Saturday 5.30pm kick-offs, although it will show some midweek games.
Both broadcasters will offer streams to subscribers on their digital platforms, including on mobile and tablet.
The Premier League have released the first 33 fixtures for TV, spanning from August to early October, and Arsenal feature more than any other club. The Gunners are on TV six times, Spurs five, Chelsea three, West Ham three, Crystal Palace twice and Watford once.
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The BBC will continue to show highlights on Match of the Day on Saturday and Sunday evenings, and the programme will also be on the BBC iPlayer but not until two days after broadcast.
The Premier League website will also show the goals and, for the first time, Twitter users in the UK and Ireland will be able to watch clips on the @SkyFootball account, following a deal to allow it to post "near-live" highlights.
LONDON CLUBS LIVE
August
Fri 11: Arsenal v Leicester (7.45pm Sky)
Sat 12: Watford v Liverpool (12.30pm Sky)
Sun 13: Newcastle v Spurs (1.30pm Sky); Man Utd v West Ham (4pm Sky)
Sat 19: Stoke v Arsenal (5.30pm BT)
Sun 20: Spurs v Chelsea (4pm Sky)
Sun 27: Liverpool v Arsenal (4pm Sky)
September
Sun 10: Burnley v C Palace (1.30pm Sky)
Mon 11: West Ham v Huddersfield (8pm Sky)
Sat 16: Crystal Palace v Southampton (12.30pm Sky); Spurs v Swansea (5.30pm BT)
Sun 17: Chelsea v Arsenal (1.30pm Sky)
Sat 23: West Ham v Spurs (12.30pm Sky)
Mon 25: Arsenal v West Brom (8pm Sky)
Sat 30: Huddersfield v Spurs (12.30pm Sky); Chelsea v Man City (5.30pm BT)
October
Sun 1: Arsenal v Brighton (12pm BT)
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